Product ID:AMMONIUM METAVANADATE, A714
MSDS Date:02/25/1992
FSC:6810
NIIN:00N038395
MSDS Number: BQXLL

FISHER SCIENTIFIC

1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100;800-424-9300(CHEMTREC)

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

CEREBROSPINAL FLUID PRESS.FOR INTRAMUSCULAR

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HRS. DILUTE EACH DOSE W/EQUAL VOL OF 1%

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HANDBOOK OF POIS, 11TH ED.). ANTIDOTE SHLD BE ADMIN

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VANADIUM CMPDS MAY CAUSE

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160 MG/KG WAS LETHAL TO RATS.NO

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GREENISH DISCOLORATION OF TONGUE, GI DISTURB, AND

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NERVOUSNESS, PSYCHIC DISTURB, VERTIGO & CONVULSNS.

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DESCRIBED IN ACUTE EXPOS. SENSIT RXNS MAY

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PROLONGED CONTACT MAY CAUSE CONJUNCTIVITIS.

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OPER IN PRESS-DEMAND/OTHER POS PRESS MODE OR

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MODE. FOR FURTHER RESPIRATORY PROTECTION, CONTACT

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VANADIC ACID, AMMONIUM SALT; (AMMONIUM METAVANADATE) (SARA

CAS: 7803-55-6

RTECS: YW0875000

Fraction By Weight: 100%

OSHA PEL 0.05 MG/M3

ACGIH TLV: 0.05 MG/M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SHOULD PROVIDE AN EYE WASH FOUNTAIN WITHIN THE

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AT LST 15 MINS, OCCAS LIFTING UPPER & LOWER

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REMOVE BY GASTRIC LAVAGE OR EMESIS.

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DEPRESSED.DO NOT PERFORM GASTRIC LAVAGE/EMESIS IF

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OF POISONING, 12TH ED.). ADMIN OF GASTRIC

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FOLLOWING ANTIDOTE HAS BEEN RECOM. HOWEVER, DECISION

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& ACTUAL DOSE REQD SHOULD BE MADE BY QUALIFIED MED

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DAY.CALCIUM DISODIUM EDETATE MAY BE USEFUL.IT IS

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0.125 MOL OF 20% SOLN PER KG OF BODY WT)IN 250-500 ML

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DOSE SHOULD NOT EXCEED 50 MG/KG/DAY. DRUG SHOULD BE

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COURSES SHLD NOT EXCEED 50 MG/KG/DAY. DAILY

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BE REDUCED IF ANY UNUSUAL URINARY FINDINGS APPEAR.

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LD50 LC50 Mixture:LD50 (ORAL,RAT): 160 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE RESP IRRIT IN
CONCS AS LOW AS 0.04 MG/M3. INHAL OF VANADIUM CMPDS MAY CAUSE
GREENISH-BLACK DISCOLORATION OF TONGUE, METALLIC TASTE, RHINITIS,
SORE THROAT, COUGH, DYSPNEA, BRONC H, EXPECTORATION, CHEST PAIN,
PULM EDEMA,& PNEUM. INDIV WHO RECOVER MAY EXPERIENCE PERSISTENT
BRONCH (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: RESEMBLING ASTHMA.EFTS ON NERV SYS
INCL HDCH,TREMORS OF EXTREMITIES, NERVOUSNESS, PSYCHIC DISTURB,
VERTIGO/CONVULSNS. SENSIT MAY OCCUR IN PREVIOUSLY EXPOS INDIV.
SKIN:VANADIUM CMPDS MAY CAUS E IRRIT W/ECZEMATOUS-TYPE LESIONS,
PROFOUND ITCHING & GENERALIZED URTICARIA.SENSIT DERM MAY OCCUR IN
PREVIOUSLY (ING 17)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED.IF BRTHG HAS
STOPPED, PERFORM ARTF RESP.KEEP PERSON WARM & AT REST. TREAT SYMP &
SUPPORTIVELY. GET MED ATTN IMMED.SKIN: REMOVE CONTAMD CLTHG & SHOES
IMM ED.WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LRG AMTS OF WATER
UNTIL NO EVIDENCE OF CHEM REMAINS (APPROX 15-20 MINS). GET MED ATTN
IMMED. EYE:WASH IMMED W/LRG AMTS OF WATER/NORM SALINE FOR (ING 3)

Extinguishing Media:EXTINGUISH USING AGENT SUITABLE FOR TYPE OF
SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE
AREA IF POSS. AVOID BRTHG VAPS/DUSTS; KEEP UPWIND.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.

Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE (FIBERBOARD)
CONTAINERS FOR RECLAMATION OR LATER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A TIGHTLY CLOSED CNTNR.
OBSERVE ALL FEDERAL, STATE AND LOC REGULATIONS WHEN STORING OF
SUBSTANCE. FOR ASSIST, CONT DISTRICT DIRECTOR OF EPA.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:SPECIFIC RESP ARE RECOM BASED ON CONTAM LEVS
FOUND IN WORK PLACE,MUST BE BASED ON SPECIFIC OPER,MUST NOT EXCEED
WORKING LIMITS OF RESP & BE JOINTLY APPRVD BY NIOSH/MSHA. ANY
NIOSH/MSHA APPRVD TYPE 'C' SUPP-AIR RESP W/FULL FACEPIECE (ING 23)
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO
MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EMPLOYEE MUST WEAR APPROP PROT (IMPERVIOUS)
CLTHG & EQUIP TO PVNT RPTD/PRLNGD SKIN CONT W/SUBSTANCE. WHERE
THERE(SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MP:392F,200C DECOMPOSES. WASTE DISP METH:IMMED AT (800) 424-8802/(202)
426-2675 IN METROPOLITAN WASHINGTON, D.C. AREA (40 CFR 302.6).
OBSERVE ALL FED,ST & LOC REGS WHEN DISP OF SUBSTANCE.FOR ASSIST, C
ONT DISTRICT DIRECTOR OF EPA. OTHER PROT EQUIP: IS POSS THAT
EMPLOYEE'S EYES MAY BE EXPOS TO SUBSTANCE, EMPLOYER (ING 2)

Melt/Freeze Pt:M.P/F.P Text:SUPP DATA
Spec Gravity:2.326
Solubility in Water:0.52 @ 15C
Appearance and Odor:WHITE OR SLIGHTLY YELLOW CRYSTALLINE POWDER.

Stability Indicator/Materials to Avoid:YES
NO DATA AVAILABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE CORROSIVE FUMES OF AMMONIA AND TOXIC OXIDES OF NITROGEN AND
VANADIUM.

Waste Disposal Methods:SARA SEC 304 REQS THAT RELS EQUAL TO/> RQ FOR
SUBSTANCE BE IMMED REPORTED TO LOC EMER PLANNING COMMITTEE & ST
EMER RESPONSE COMMISION (40 CFR 355.40).IF RELS OF SUBSTANCE IS
REPORTABLE UNDER CERCLA SE C 103,NATL RESPONSE CNTR MUST BE
NOTIFIED (SUPDAT)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.